Franklin

a| 2002016056

a| 0792375211

a| (OCoLC)ocm48810260

a| (OCoLC)48810260

a| (CStRLIN)XBCP2002016056-B

a| (PUVoyagerBIBID)3277704

a| 3277704

a| (PU)3277704-penndb-Voyager

a| DLC b| eng c| DLC d| OrLoB

a| pcc

a| QD411.8.A47 b| C48 2002

a| 547/.05 2| 21

a| The chemistry of metal alkoxides / c| by Nataliya Ya. Turova ... [and others].

a| Boston ; a| London : b| Kluwer Academic Publishers, c| [2002]

c| ©2002

a| xii, 568 pages : b| illustrations ; c| 25 cm

a| text b| txt 2| rdacontent

a| unmediated b| n 2| rdamedia

a| volume b| nc 2| rdacarrier

a| Includes bibliographical references (pages [505]-562) and index.

g| 1.1. t| Classification. General characteristic of the metal alkoxides g| 1 -- g| 1.2. t| Main steps in the development of the chemistry of metal alkoxides g| 3 -- g| 1.3. t| Application of alkoxides in sol-gel processes g| 6 -- g| Chapter 2. t| General Synthetic Approaches g| 11 -- g| 2.1. t| Reactions of metals with alcohols (method 1) g| 11 -- g| 2.2. t| Anodic oxidation of metals (method 2) g| 14 -- g| 2.3. t| Reactions of metal oxides or hydroxides with alcohols (method 3) g| 16 -- g| 2.4. t| Alcoholysis of MX[subscript n] (method 4) g| 18 -- g| 2.5. t| Metathesis reactions of MX[subscript n] with alkaline alkoxides or ammonia (method 5) g| 21 -- g| 2.6. t| Reactions of alcohol interchange or transesterification (method 6) g| 26 -- g| 2.7. t| Redox reactions of metal alkoxides: Oxidation of organometallic compounds (method 7) g| 28 -- g| Chapter 3. t| Physicochemical Properties of Alkoxides: Regularities in the Homologous Series g| 31 -- g| Chapter 4. t| Crystal and Molecular Structures of Metal Alkoxides g| 37 -- g| 4.1. t| Mononuclear complexes g| 38 -- g| 4.2. t| Binuclear complexes g| 41 -- g| 4.3. t| Trinuclear complexes g| 45 -- g| 4.4. t| Tetranuclear complexes g| 48 -- g| 4.5. t| Pentanuclear complexes g| 55 -- g| 4.6. t| Hexanuclear complexes g| 56 -- g| 4.7. t| Oligomeric alkoxides containing more than 6 nuclei g| 59 -- g| 4.8. t| Polymers g| 65 -- g| Chapter 5. t| Oxoalkoxides g| 69 -- g| Chapter 6. t| Specific Features of Physico-Chemical Behavior: [angle quotation mark, left]Coordination Polymerism[angle quotation mark, right] g| 77 -- g| Chapter 7. t| Heteroleptic Metal Alkoxides Containing Carboxylato-, [beta]-Diketonato, and Aminoalkoxide Ligands g| 87 -- g| 7.1. t| Synthesis g| 88 -- g| 7.2. t| Molecular structures g| 92 -- g| 7.3. t| Particular features of hydrolysis and thermolysis g| 94 -- g| Chapter 8. t| Adducts and Heterometallic Alkoxides g| 97 -- g| 8.1. t| Solvate complexes g| 97 -- g| 8.2. t| Heterometallic complexes g| 99 -- g| Chapter 9. t| Hydrolysis of Metal Alkoxides and Synthesis of Simple Oxides by the Sol-Gel Method g| 107 -- g| 9.1. t| Alkoxides of the metals of groups I and II g| 112 -- g| 9.2. t| Aluminum alkoxides g| 112 -- g| 9.3. t| Alkoxides of rare earth elements g| 114 -- g| 9.4. t| Germanium, tin, lead alkoxides g| 114 -- g| 9.5. t| Titanium and zirconium alkoxides g| 115 -- g| 9.6. t| Bismuth alkoxides g| 122 -- g| 9.7. t| Vanadium alkoxides g| 123 -- g| 9.8. t| Niobium and tantalum alkoxides g| 124 -- g| 9.9. t| Molybdenum and tungsten alkoxides g| 125 -- g| 9.10. t| Iron ethoxide g| 125 -- g| Chapter 10. t| Synthesis of Complex Oxides from Metal Alkoxides g| 127 -- g| 10.1. t| Barium titanate and BaTiO[subscript 3]-based solid solutions g| 129 -- g| 10.2. t| Complex niobates and tantalates g| 137 -- g| 10.3. t| Lead zirconate-titanate (PZT) and lead-lanthane zirconate-titanate (PLZT) solid solutions g| 141 -- g| 10.4. t| Bismuth strontium tantalates and niobates SrBi[subscript 2]M[superscript V subscript 2]O[subscript 9] (M[superscript V] = Nb, Ta) g| 144 -- g| 10.5. t| High-temperature superconductors g| 147 -- g| Chapter 11. t| Hybrid Organic-Inorganic Materials g| 149 -- g| 11.1. t| Systems with weak chemical interactions g| 150 -- g| 11.2. t| Systems with strong chemical interactions between components g| 153 -- g| Chapter 12. t| The Overview of Metal Alkoxide Derivatives Along the Groups of the Periodic Table g| 159 -- g| 12.1. t| Alkaline, alkaline earth, and magnesium alkoxides g| 160 -- g| 12.2. t| Copper, silver, and gold alkoxides g| 199 -- g| 12.3. t| Beryllium alkoxides g| 211 -- g| 12.4. t| Zinc, cadmium, and mercury alkoxides g| 217 -- g| 12.5. t| Aluminium alkoxides g| 224 -- g| 12.6. t| Gallium, indium, and thallium alkoxides g| 245 -- g| 12.7. t| Rare earth elements alkoxides g| 256 -- g| 12.8. t| Germanium alkoxides g| 289 -- g| 12.9. t| Tin alkoxides g| 297 -- g| 12.10. t| Lead alkoxides g| 309 -- g| 12.11. t| Titanium alkoxides g| 315 -- g| 12.12. t| Zirconium and hafnium alkoxides g| 348 -- g| 12.13. t| Thorium alkoxides g| 367 -- g| 12.14. t| Bismuth alkoxides g| 372 -- g| 12.15. t| Vanadium alkoxides g| 379 -- g| 12.16. t| Niobium and tantalum alkoxides g| 395 -- g| 12.17. t| Chromium alkoxides g| 418 -- g| 12.18. t| Molybdenum and tungsten alkoxides g| 425 -- g| 12.19. t| Uranium and transuranium elements alkoxides g| 434 -- g| 12.20. t| Manganese alkoxides g| 469 -- g| 12.21. t| Technetium and rhenium alkoxides g| 473 -- g| 12.22. t| Iron alkoxides g| 475 -- g| 12.23. t| Cobalt and nickel alkoxides g| 490 -- g| 12.24. t| Alkoxide derivatives of platinum metals g| 497.

a| Acquired for the Penn Libraries with assistance from the Rosengarten Family Fund.

a| The study of the chemistry of metal alkoxides, which began more than 100 years ago, is now experiencing a renaissance due to the broad application of these compounds as molecular precursors in the synthesis of advanced technological materials based on simple and complex oxides. The solution of this problem is occupying a wide circle of inorganic chemists, technologists specializing in fine synthesis in nonaqueous media, and those working on the production of films and coatings. The application of metal alkoxides in the first step of sol-gel technology (based on hydrolysis of alkoxides with the subsequent dehydration of the hydrated oxides formed) is addressed in this monograph covering the modern literature devoted to all the steps of this process.

a| This book is devoted to the general questions of the chemistry of metal alkoxides -- the synthetic routes to them (both laboratory and technology) physiochemical properties, structure, specific features of single groups of alkoxides, theoretical principles of their use for the preparation of simple and complex oxides by the sol-gel method, and major directions of the application of this method in the preparation of functional materials. Also included are the derivatives of single elements of first through eighth groups of the Periodic Table. The tables contain the major data on the alkoxides, phenoxides, siloxides, derivatives of polyatomic alcohols, and phenols -- their composition, structure, preparation techniques, and major physiochemical characteristics. These tables allow the book to be used as a handbook permitting a quick and essentially complete acquaintance with the distinct compounds and the literature describing them.

a| Alkoxides. 0| http://id.loc.gov/authorities/subjects/sh2001008313

a| Alkoxides. 2| fast 0| http://id.worldcat.org/fast/805421

a| Turova, Nataliya Ya. 0| http://id.loc.gov/authorities/names/n2002017900

a| Rosengarten Family Fund. 5| PU

3| The Rosengarten Family Fund Home Page u| http://hdl.library.upenn.edu/1017.12/366323

a| MARCIVE 2022

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