Franklin

Cobalt catalysis in organic synthesis methods and reactions / edited by Marko Hapke and Gerhard Hilt.

Publication:
Weinheim : Wiley-VCH, 2020.
Format/Description:
Book
1 online resource (483 p.)
Subjects:
Cobalt catalysts.
Organic compounds -- Synthesis.
Contents:
Cover
Title Page
Copyright
Contents
Preface
Chapter 1 Introduction to Cobalt Chemistry and Catalysis
1.1 Introduction
1.2 Organometallic Cobalt Chemistry, Reactions, and Connections to Catalysis
1.2.1 Cobalt Compounds and Complexes of Oxidation States +3 to -1
1.2.1.1 Co(III) Compounds
1.2.1.2 Co(II) Compounds
1.2.1.3 Co(I) Compounds
1.2.1.4 Co(0) Compounds
1.2.1.5 Co(-I) Compounds
1.2.2 Bioorganometallic Cobalt Compounds
1.3 Applications in Organic Synthesis and Catalytic Transformations
1.4 Conclusion and Outlook
Abbreviations
References
Chapter 2 Homogeneous Cobalt-Catalysed Hydrogenation Reactions
2.1 Introduction
2.2 Hydrogenation of C C Multiple Bonds (Alkenes, Alkynes)
2.3 Hydrogenation of Carbonyl Compounds (Ketones, Aldehydes, Carboxylic Acid Derivatives, CO2)
2.3.1 Ketones and Aldehydes
2.3.2 Carboxylic Acid Derivatives (Acids, Esters, Imides)
2.3.3 Hydrogenation of Carbon Dioxide
2.4 Hydrogenation of C X Multiple Bonds (Imines, Nitriles)
2.4.1 Nitrile Hydrogenation
2.4.2 Imine Hydrogenation
2.4.3 Hydrogenation of N-Heterocycles
2.5 Summary and Conclusions
2.6 Selected Experimental Procedures
2.6.1 Synthesis of Cobalt Complex [(PNHPCy)Co(CH2SiMe3)]BArF4 (8a)
Abbreviations
References
Chapter 3 Synthesis of C C Bonds by Cobalt-Catalysed Hydrofunctionalisations
3.1 Introduction
3.2 Cobalt-Catalysed C C Bond Formations via Hydrofunctionalisation
3.2.1 Hydroformylation
3.2.2 Hydroacylation
3.2.3 Hydrovinylation
3.2.4 Hydroalkylation
3.2.5 Hydrocyanation
3.2.6 Hydrocarboxylation
3.3 Summary and Conclusions
Abbreviations
References
Chapter 4 Cobalt-Catalysed C-H Functionalisation
4.1 Introduction
4.2 Low-valent Cobalt Catalysis
4.2.1 C-H Functionalisation with In Situ-Reduced Cobalt Catalysts
4.2.1.1 Hydroarylation of Alkynes and Alkenes
4.2.1.2 C-H Functionalisation with Electrophiles
4.2.1.3 C-H Functionalisation with Organometallic Reagents
4.2.1.4 C-H Functionalisation via 1,4-Cobalt Migration
4.2.1.5 Hydroacylation
4.2.2 C-H Functionalisation with Pincer-Type Ligands and Related Well-Defined Cobalt Catalysts
4.3 High-valent Cobalt Catalysis
4.3.1 Chelation-Assisted C-H Functionalisation with Cp*CoIII Catalysts
4.3.1.1 C H Addition to Polar C X Bonds
4.3.1.2 Reaction with Alkynes, Alkenes, and Allenes
4.3.1.3 Reaction with Formal Nitrene or Carbene Precursors
4.3.1.4 Reaction with E-X-type Electrophiles
4.3.1.5 Miscellaneous
4.3.2 Bidentate Chelation-Assisted C-H Functionalisation with CoIII Catalysts
4.3.2.1 Reaction with Alkynes, Alkenes, and Allenes
4.3.2.2 Dehydrogenative Cross-coupling Reactions
4.3.2.3 Carbonylation and Related Transformations
4.3.2.4 Miscellaneous Transformations
4.3.3 Miscellaneous
4.4 Summary and Outlook
Abbreviations
References
Notes:
Description based upon print version of record.
Chapter 5 Low-valent Cobalt Complexes in C-X Coupling and Related Reactions
Includes bibliographical references.
Electronic reproduction. Hoboken, N.J. Available via World Wide Web.
Contributor:
Hapke, Marko.
Hilt, Gerhard.
Wiley InterScience (Online service)
Other format:
Print version: Hapke, Marko Cobalt Catalysis in Organic Synthesis : Methods and Reactions
ISBN:
9783527814855
352781485X
9783527814831
3527814833
9783527344505
Publisher Number:
99984473627
Access Restriction:
Restricted for use by site license.
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